One of my favorite people in the startup space is Jason Calacanis. Every week he does a video/call in show(ThisWeekInStartups.com) on uStream.tv. There's great stuff in there and I recommend it to everyone.

Here's the live version of this weeks show. Streaming live video by Ustream
Update: This was a great show. Plenty of controversy (as too be expected by Jason). He rails on Keiretsu for trying to charge startups to pitch to Angel investors.